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Filters: Tags: carbon isotope analysis (X) > partyWithName: Woods Hole Coastal and Marine Science Center (X)

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Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to test the hypothesis that chemoclines associated with salinity gradients (haloclines) within the flooded cave networks of the karst subterranean estuary are sites of methane oxidation. Two field trips were carried out to the fully-submerged cave system located 6.6 km inland from the coastline in January 2015 and January 2016. Vertical chemical profiles across the water column haloclines were obtained using the OctoPiPi (OPP), a high-resolution water sampler built by the U.S. Geological Survey (USGS). The sampling efforts resulted in cm-scale profiles of major ions (e.g., chloride and sulfate), as well as concentrations...
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The accretion history of fringing salt marshes located on the south shore of Cape Cod is reconstructed from sediment cores collected in low and high marsh vegetation zones. These marshes are micro-tidal, with a mean tidal range of 0.442 m. Their location within protected embayments and the absence of large rivers results in minimal sediment supply and a dominance of organic matter contributions to sediment peat. Age models based on 210-lead and 137-cesium are constructed to evaluate how vertical accretion and carbon burial rates have changed over the past century. The continuous rate of supply age model was used to age date 11 cores (10 low marsh and 1 high marsh) across four salt marshes. Both vertical accretion...
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Coastal wetlands are major global carbon sinks, however, they are heterogeneous and dynamic ecosystems. To characterize spatial and temporal variability in a New England salt marsh, static chamber measurements of greenhouse gas (GHG) fluxes were compared among major plant-defined zones (high marsh dominated by Distichlis spicata and a zone of invasive Phragmites australis) during 2013 and 2014 growing seasons. Two sediment cores were collected in 2015 from the Phragmites zone to support previously reported core collections from the high marsh sites (Gonneea and others 2018). Collected cores were up to 70 cm in length with dry bulk density ranges from 0.04 to 0.33 grams per cubic centimeter and carbon content 22.4%...
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The San Juan Bay Estuary, Puerto Rico, contains mangrove forests that store significant amounts of organic carbon in soils and biomass. There is a strong urbanization gradient across the estuary, from the highly urbanized and clogged Caño Martin Peña in the western part of the estuary, a series of lagoons in the center of the estuary, and a tropical forest reserve (Piñones) in the easternmost part with limited urbanization. We collected sediment cores to determine carbon burial rates and vertical sediment accretion from five sites in the San Juan Bay Estuary. Cores were radiometrically-dated using lead-210 and the Plum age model. Sites had soil C burial rates ranging from 50 grams per meter squared per year (g m-2...
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The Herring River estuary in Wellfleet, Cape Cod, Massachusetts, has been tidally restricted for more than a century by a dike constructed near the mouth of the river. Upstream from the dike, the tidal restriction has caused the conversion of salt marsh wetlands to various other ecosystems including impounded freshwater marshes, flooded shrub land, drained forested upland, and brackish wetlands dominated by Phragmites australis. This estuary is now managed by the National Park Service, which plans to replace the aging dike and restore tidal flow to the estuary. To assist National Park Service land managers with restoration planning, the U.S. Geological Survey collected fourteen sediment cores from different ecosystems...
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Nineteen sediment cores were collected from five salt marshes on the northern shore of Cape Cod where previously restricted tidal exchange was restored to part of the marshes. Cores were collected in duplicate from two locations within each marsh complex: one upstream and one downstream from the former tidal restriction (typically caused by an undersized culvert or a berm). The unaltered, natural downstream sites provide a comparison against the historically restricted upstream sites. The sampled cores represent a chronosequence of restoration occurring between 2001–10. Collected cores were up to 168 cm in length with dry bulk density ranging from 0.04 to 2.62 grams per cubic centimeter and carbon content 0.12 %...
Categories: Data; Tags: Barnstable County (606927), Bass Creek (617465), Boat Meadow River (616844), Cape Cod (606914), Cape Cod Canal (619536), All tags...
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A critical question for assessing global greenhouse gas budgets is how much of the methane that escapes from seafloor cold seep sites to the overlying water column eventually crosses the sea-air interface and reaches the atmosphere. The issue is particularly important in Arctic Ocean waters since rapid warming there increases the likelihood that gas hydrate--an ice-like form of methane and water stable at particular pressure and temperature conditions within marine sediments--will break down and release its methane to the overlying ocean. Some researchers have even proposed the possibility of an Arctic methane catastrophe characterized by wholesale breakdown of gas hydrates in marine sediments and release of the...
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A discrete sample introduction module (DSIM) was developed and interfaced to a cavity ring-down spectrometer to enable measurements of methane and CO2 concentrations and 13C values with a commercially available cavity ring-down spectrometer (CRDS). The DSIM-CRDS system permits the analysis of limited volume (5 - 100-ml) samples ranging six orders-of-magnitude from 100% analyte to the lower limit of instrument detection (2 ppm). We demonstrate system performance for methane by comparing concentrations and 13C results obtained by the DSIM and traditional methods for a variety of sample types, including low concentration (nanomolar) seawater and high concentration (> 90%) natural gas. The expansive concentration range...
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Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to investigate how regional meteorology and hydrology control methane dynamics in karst subterranean estuaries. Three field trips were carried out in January 2015, June 2015, and January 2016 to obtain year-long high-resolution temporal records of water chemistry and environmental parameters below and above the surface at a site (Cenote Bang) within the Ox Bel Ha cave network. These efforts resulted in chemical records of dissolved methane concentrations and its stable carbon isotopic content and major ion concentrations (i.e., chloride and sulfate) in approximately 2.5-day resolution from January 2015 to January...
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Coastal wetlands in Tampa Bay, Florida, are important ecosystems that deliver a variety of ecosystem services. Key to ecosystem functioning is wetland response to sea-level rise through accumulation of mineral and organic sediment. The organic sediment within coastal wetlands is composed of carbon sequestered over the time scale of the wetland’s existence. This study was conducted to provide information on soil accretion and carbon storage rates across a variety of coastal ecosystems that was utilized in the Tampa Bay Blue Carbon Assessment (ESA, 2017; linkage below). Ten sediment cores were collected from six Tampa Bay wetland sites in October 2015 (maximum core length 40 centimeters). Three main vegetation types...
Categories: Data; Tags: 137-cesium, 210-lead, City of Saint Petersburg (2405401), City of Tampa (2405568), Double Branch Bay (281701), All tags...


    map background search result map search result map Data and calculations to support the study of the sea-air flux of methane and carbon dioxide on the West Spitsbergen margin in June 2014 Collection, analysis, and age-dating of sediment cores from salt marshes on the south shore of Cape Cod, Massachusetts, from 2013 through 2014 Temporal hydrologic and chemical records from the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula, from January 2015 to January 2016 Vertical chemical profiles collected across haloclines in the water column of the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula in January 2015 and January 2016 Collection, analysis, and age-dating of sediment cores from mangrove wetlands in San Juan Bay Estuary, Puerto Rico, 2016 Collection, analysis, and age-dating of sediment cores from Herring River wetlands and other nearby wetlands in Wellfleet, Massachusetts, 2015–17 Collection, analysis, and age-dating of sediment cores from natural and restored salt marshes on Cape Cod, Massachusetts, 2015-16 Comparison of methane concentration and stable carbon isotope data for natural samples analyzed by discrete sample introduction module - cavity ring down spectroscopy (DSIM-CRDS) and traditional methods Static chamber gas fluxes and carbon and nitrogen isotope content of age-dated sediment cores from a Phragmites wetland in Sage Lot Pond, Massachusetts, 2013-2015 Static chamber gas fluxes and carbon and nitrogen isotope content of age-dated sediment cores from a Phragmites wetland in Sage Lot Pond, Massachusetts, 2013-2015 Collection, analysis, and age-dating of sediment cores from mangrove wetlands in San Juan Bay Estuary, Puerto Rico, 2016 Collection, analysis, and age-dating of sediment cores from Herring River wetlands and other nearby wetlands in Wellfleet, Massachusetts, 2015–17 Collection, analysis, and age-dating of sediment cores from salt marshes on the south shore of Cape Cod, Massachusetts, from 2013 through 2014 Vertical chemical profiles collected across haloclines in the water column of the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula in January 2015 and January 2016 Temporal hydrologic and chemical records from the Ox Bel Ha cave network within the coastal aquifer of the Yucatan Peninsula, from January 2015 to January 2016 Collection, analysis, and age-dating of sediment cores from natural and restored salt marshes on Cape Cod, Massachusetts, 2015-16 Data and calculations to support the study of the sea-air flux of methane and carbon dioxide on the West Spitsbergen margin in June 2014 Comparison of methane concentration and stable carbon isotope data for natural samples analyzed by discrete sample introduction module - cavity ring down spectroscopy (DSIM-CRDS) and traditional methods