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Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings—in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predominantly from two classes of herbicides—triazines and chloroacetanilides; insecticides and fungicides were not present in the shallow ground water. In most samples, pesticide degradates greatly exceeded the concentrations of parent pesticide. In samples from Nebraska, the parent pesticide atrazine [6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine]...
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We have developed a screening tool to visualize and conceptualize the filtering properties of a layered vadose zone. Climate projections indicate that rainfall timing and magnitude may change and impact groundwater resources. This increases the importance of understanding how the vadose zone filters infiltration variability and ultimately affects recharge and groundwater resources. An approximate solution for the filtering of surface forcings through soil layers was developed previously, and the soil and conditions where its approximations are appropriate was evaluated. Here we present a screening tool based on the solution for estimating how periodic infiltration forcings filter in a layered vadose zone for different...
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Selenium stable isotope ratios are known to shift in predictable ways during various microbial, chemical, and biological processes, and can be used to better understand Se cycling in contaminated environments. In this study we used Se stable isotopes to discern the mechanisms controlling the transformation of oxidized, aqueous forms of Se to reduced, insoluble forms in sediments of Se-affected environments. We measured 80Se/76Se in surface waters, shallow ground waters, evaporites, digested plants and sediments, and sequential extracts from several sites where agricultural drainage water is processed in the San Joaquin Valley of California. Selenium isotope analyses of samples obtained from the Tulare Lake Drainage...
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This study evaluated decadal-scale changes of nitrate concentrations in groundwater samples collected by the USGS National Water-Quality Assessment Program from 495 wells in 24 well networks across the USA in predominantly agricultural areas. Each well network was sampled once during 1988-1995 and resampled once during 2000-2004. Statistical tests of decadal-scale changes of nitrate concentrations in water from all 495 wells combined indicate there is a significant increase in nitrate concentrations in the data set as a whole. Eight out of the 24 well networks, or about 33%, had significant changes of nitrate concentrations. Of the eight well networks with significant decadal-scale changes of nitrate, all except...
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stimates of C storage in mountainous regions are rare. Forest–meadow ecotones in subalpine ecosystems, which contain a mosaic of forests and meadows, may be particularly sensitive to future changes in climate and are therefore important to include in estimates of terrestrial C storage. In this study, we quantified soil C and ecosystem C pools in subalpine forest and meadow soils of the northeastern (NE, dry climate) and southwestern (SW, wet climate) Olympic Mountains. Carbon concentrations of mineral soil are relatively high in upper horizons, ranging from 43 to 142 g kg−1 in NE soils and 27 to 162 g kg−1 in SW soils. Northeastern meadow soils store more C than NE forests ( P = 0.009), while SW forest soils store...
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